High Performance Tubular Solid Oxide Fuel Cell Based on Ba0.5Sr0.5Ce0.6Zr0.2Gd0.1Y0.1O3-? Proton Conducting Electrolyte

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dc.contributor.authorAmiri, Taghi
dc.contributor.authorSingh, Kalpana
dc.contributor.authorSandhu, Navjot Kaur
dc.contributor.authorHanifi, Amir Reza
dc.contributor.authorEtsell, Thomas H.
dc.contributor.authorLuo, Jing-Li
dc.contributor.authorThangadurai, Venkataraman
dc.contributor.authorSarkar, Partha
dc.date.accessioned2020-02-28T22:22:01Z
dc.date.available2020-02-28T22:22:01Z
dc.date.issued2018-07-07
dc.description.abstractIn this work, synthesis and characterization of an anode supported tubular solid oxide fuel cell based on Ba0.5Sr0.5Ce0.6Zr0.2Gd0.1Y0.1O3-? (BSCZGY) electrolyte has been investigated. Anode-supported Ni - yttria-stabilized zirconia (YSZ) anode was fabricated via slip casting; BSCZGY electrolyte and BSCZGY - La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) composite cathode were coated on support using dip coating, respectively. The chemical compatibility of fuel cell components at sintering temperatures has been investigated by powder X-ray diffraction, and no severe reactions were detected. Electrochemical examination under air/H2 + 3 vol. % H2O showed superior performance achieving a maximum power density of 1 W/cm2 at 850°C, among the best compared to tubular – geometry oxygen conductor solid oxide fuel cells reported earlier and one of the highest reported for a proton conductor electrolyte in literature. Electrochemical impedance spectroscopy was used to examine the electrochemical performance of the full cell at different temperatures, and a detailed analysis was done to distinguish the contribution of ohmic and polarization resistances of the cell. ASR values were 3.47 ?.cm2, 1.81 ?.cm2, 1.23 ?.cm2, and 1.05 ?.cm2 at 600, 700, 800, and 850°C, respectively. Analysis of activation energy associated with charge and mass transfer based on fitting of impedances revealed that concentration polarization is the major contributor to the total resistance. The long-term stability for more than 96 hours of operation under load showed no significant degradation, which demonstrated the steady behavior of the cell.
dc.identifier.citationAmiri, T., Singh, K., Sandhu, N. K., Hanifi, A. R., Etsell, T. H., Luo, J.-L., Thangadurai, V., & Sarkar, P. (2018). High Performance Tubular Solid Oxide Fuel Cell Based on Ba0.5Sr0.5Ce0.6Zr0.2Gd0.1Y0.1O3-?Proton Conducting Electrolyte. Journal of The Electrochemical Society, 165(10), F764–F769. https://doi.org/10.1149/2.0331810jes
dc.identifier.doi10.1149/2.0331810jes
dc.identifier.issn1945-7111
dc.identifier.urihttp://hdl.handle.net/1880/111700
dc.identifier.urihttps://dx.doi.org/10.11575/PRISM/37619
dc.language.isoenen
dc.language.isoeng
dc.publisherThe Electrochemical Society
dc.publisher.departmentDepartment of Chemistry
dc.publisher.facultyScienceen
dc.publisher.hasversionpublishedVersion
dc.publisher.institutionUniversity of Calgaryen
dc.publisher.policyhttp://ecsdl.org/site/misc/oa.xhtml#9
dc.rightsUnless otherwise indicated, this material is protected by copyright and has been made available with authorization from the copyright owner. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.en
dc.rights© The Author(s) 2018. Published by ECS.
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.titleHigh Performance Tubular Solid Oxide Fuel Cell Based on Ba0.5Sr0.5Ce0.6Zr0.2Gd0.1Y0.1O3-? Proton Conducting Electrolyte
dc.typejournal article
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