Detection of triacetone triperoxide by thermal decomposition peroxy radical chemical amplification coupled to cavity ring-down spectroscopy
Date
2018-05-04
Journal Title
Journal ISSN
Volume Title
Publisher
Springer
Abstract
Triacetone triperoxide (TATP) is frequently used in improvised explosive devices because of its ease of manufacture and tremendous explosive force. In this paper, we describe a new method for detection of TATP, thermal decomposition peroxy radical chemical amplification cavity ring-down spectroscopy (TD-PERCA-CRDS). In this method, air is sampled through a heated inlet to which ~ 1 ppmv nitric oxide (NO) is added. To verify the purity of synthetic standards, the mid-infrared spectrum of TATP vapor was recorded. The thermal decomposition of TATP is shown to produce radicals which oxidize NO to nitrogen dioxide (NO2), whose concentration increase is monitored by optical absorption at 405 nm using a blue diode laser CRDS. The sensitivity could be improved through addition of ~ 1% ethane (C2H6), which fuels catalytic conversion of NO to NO2. The limit of detection of TD-PERCA-CRDS with respect to TATP is 22 pptv (1 s data), approximately six orders of magnitude below TATP's saturation vapor pressure. Insights into the mechanism of TATP thermal decomposition, TD-PERCA-CRDS interferences, and the suitability of TD-PERCA-CRDS as a peroxy radical explosive detection method at security check points are discussed.
Description
This is a post-peer-review, pre-copyedit version of an article published in Analytical and Bioanalytical Chemistry. The final authenticated version is available online at: https://doi.org/10.1007/s00216-018-1072-0
Keywords
Triacetone triperoxide, TATP, trace sensing, peroxy radical chemical amplification, PERCA, cavity ring-down spectroscopy, CRDS, mechanism of TATP thermal decomposition, mid-infrared spectrum
Citation
Taha, Y. M., Saowapon, M. T., & Osthoff, H. D. (2018). Detection of triacetone triperoxide by thermal decomposition peroxy radical chemical amplification coupled to cavity ring-down spectroscopy. Analytical and bioanalytical chemistry, 410(17), 4203-4212.